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Synthesis of iso-artemisia and artemisia ketones from ethylenic dithioesters.

โœ Scribed by P. Gosselin; S. Masson; A. Thuillier


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
151 KB
Volume
19
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


We have recently shown that both carbophilic and thiophilic additions of Grignard reagents to dithioesters could be conveniently used for the synthesis of S-unsa-') ICHJ 7 -


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Nortaylorione a new nor-sesquiterpene, was identified among minor components of Artemisia annua (hybrid plants) essential oil. Its relative and absolute configurations were determined by GC and GC/MS equipped with a chiral column and coinjecting the essential oil with synthetic standards (racemic an