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General Synthesis of Ketones from Carboxylic Esters and Carboxamides by Use of Mixed Organolithium-Magnesium Reagents: Syntheses of Artemisia Ketone

✍ Scribed by Charles Fehr; José Galindo; Roland Perret

Publisher: John Wiley and Sons
Year: 1987
Tongue: German
Weight: 474 KB
Volume: 70
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19870700710

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✦ Synopsis

Reaction of

Carboxylic Esters and in situ Generated Carboxamides Yielding

Kerones

Ketone/alcohol

📜 SIMILAR VOLUMES

Synthesis of (E)-1-Propenyl Ketones from

Synthesis of (E)-1-Propenyl Ketones from Carboxylic Esters and Carboxamides by Use of Mixed Organolithium-Magnesium Reagents. Synthesis of α-Damascone, β-Damascone, and β-Damascenone

✍ Charles Fehr; José Galindo 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 German ⚖ 488 KB 👁 2 views

For a special (intramolecular) case, see [5]. Vol.69 (1986) 229 ') The diethylamides corresponding to esters 1-3 are unreactive. ( E ) / ( Z ) % 9:l. We assume that the major silylenol ether 12 formed has the (E)-configuration (see [15]).