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Synthesis of Indene and Naphthalene Derivatives by a Palladium-Catalyzed Domino Carbopalladation/Cyclization/Coupling Process

✍ Scribed by Li-Na Guo; Xin-Hua Duan; Jie Hu; Hai-Peng Bi; Xue-Yuan Liu; Yong-Min Liang

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
188 KB
Volume
2008
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

Highly substituted indene and naphthalene derivatives have been readily prepared in good‐to‐high yields by a palladium‐catalyzed domino reaction. This domino reaction involves a Heck carbopalladation/cyclization/coupling process. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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## Abstract A novel palladium‐catalyzed synthesis of substituted 3‐methylene‐3__H__‐indoles from readily accessible alkynylimines has been developed. A wide variety of 2‐fluoroalkyl‐3‐methylene‐3__H__‐indoles were synthesized in moderate to good yields through this cascade carbopalladation/CH acti