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Synthesis of Imines From N-(1-Halogenoalkyl)Heteroarylium Salts

✍ Scribed by A. Maquestiau; E. Anders; J.-J. Vanden Eynde; P. D'Orazio; A. Mayence

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
235 KB
Volume
98
Category
Article
ISSN
0037-9646

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In the absence of any added acidic catalyst quinone acetals as well as simple ketone and aldehyde acetals react with a variety of substituted anilines to form imines [Eq. (a)]. Contrary to what is expected from arguments based on their nucleophilicity, the most reactive anilines are those bearing el