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ChemInform Abstract: Direct Synthesis of N-Arylquinone Imine Acetals and Quinol Imines from Acetals.

✍ Scribed by M. Carmen Carreno; Juan M. Cuerva; Maria Ribagorda; Antonio M. Echavarren


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Direct Synthesis of N-Arylquinone Imine
✍ M. Carmen CarreΓ±o; Juan M. Cuerva; MarΓ­a Ribagorda; Antonio M. Echavarren πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 115 KB πŸ‘ 2 views

In the absence of any added acidic catalyst quinone acetals as well as simple ketone and aldehyde acetals react with a variety of substituted anilines to form imines [Eq. (a)]. Contrary to what is expected from arguments based on their nucleophilicity, the most reactive anilines are those bearing el