Synthesis of illudins II. Functionalized illudane
✍ Scribed by Takeshi Matsumoto; Haruhisa Shirahama; Akitami Ichihara; Hyonsobb Shin; Shohei Kagawa; Noriki Ito; Toshiaki Hisamitsu; Toshihiro Kamada; Fujio Sakan; Ken'ichi Saito; Shuji Nishida; Sōjiro Matsumoto
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 205 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
In an earlier paper 2) a stereospecific synthesis of the compound III, which
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In a previous paper, the total synthesis of dl-llludln M (10) was reported. In this paper we wish to describe synthesis of dl-llludln S dlacetate (Q)2\*3'4 through a similar sequence of reactions. Since recon-version of optically active llludln S dlacetate to llludln S by treatment with aqueous sodi
The structure8 of illudin S '#\*) (lsmpterol) and illudin M2) , antibiotic nubatances from fungi, have been ahown to be I and II, respectively. We should like to report the syntheaia of the compound (III), which haa none structural features and the unique non-isoprenoid rkeleton of illudina.
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