The synthesis of tetrakis (1,1-dimethyl-2-trimethylammonium)ethylphthalocyaninato Zn(II) tetraiodide 2--a new cationic phthalocyanine--is reported as well as its photophysical properties in water, relevant for the use of this dye as photodynamic sensitizer. The hydrophobicity of the macrocycle leads
Synthesis and properties of cobaltacarborane-functionalized Zn(II)-phthalocyanines
✍ Scribed by Hairong Li; Frank R. Fronczek; M. Graça H. Vicente
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- French
- Weight
- 311 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The syntheses of two new A 3 B-type Zn(II)-phthalocyanines (Zn-Pcs) containing either one or two cobaltacarborane residues are reported, and the X-ray structure of a key phthalonitrile precursor is presented. The Zn-Pcs are highly soluble and exist as monomers in polar organic solvents.
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