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Synthesis of hyperbranched poly(tert-butyl acrylate) by self-condensing atom transfer radical polymerization of a macroinimer

✍ Scribed by Guanglou Cheng; Peter F. W. Simon; Markus Hartenstein; Axel H. E. Müller


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
119 KB
Volume
21
Category
Article
ISSN
1022-1336

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The `living' radical polymerization of 2-(2',3',4',6'-tetra-O-acetyl-b-D-glucopyranosyloxy)ethyl acrylate (AcGEA) by atom transfer radical polymerization (ATRP) is reported. It has been found that the polymerization kinetics are ®rst-order, the molecular weights increase linearly with conversion, an