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Synthesis of Hydroxy(or Hydroperoxy)-Substituted 1,2,4-Trioxacycloalkanes by the Ozonolysis of Unsaturated Hydroperoxy Acetals

โœ Scribed by Ushigoe, Yoshihiro; Torao, Yuko; Masuyama, Araki; Nojima, Masatomo


Book ID
121400417
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
241 KB
Volume
62
Category
Article
ISSN
0022-3263

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Oxy-functionalized 1,2,4-trioxanes or 1,2,4-trioxepanes were produced by either autoxidation of the unsaturated hydroperoxy acetals 1, or the acid-catalyzed cyclization of epoxy hydroperoxides 9 which were readily prepared from 1. By the appropriate choice of cyclization procedure, the structures of