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Synthesis of Hydrophenanthrene Natural Products. An Improved Synthesis of 13-Substituted Dehydroabietane Derivatives from Dehydroabietic Acid

✍ Scribed by Jurgens, Alex R.; Mcchesney, James D.


Book ID
126722111
Publisher
Taylor and Francis Group
Year
1993
Tongue
English
Weight
308 KB
Volume
2
Category
Article
ISSN
1057-5634

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## Abstract We describe a flexible, stereocontrolled synthesis of enantiomerically pure substituted cyclopentenes and cyclopentanes ‐ including 11α‐hydroxy‐13‐oxaprostanoic acid **20** ‐ (−)‐quinic acid __via__ an acyclic precursor **6** by an intramolecular aldolisation‐dehydration reaction.