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Synthesis of homoleptic silylphosphido complexes (M[P(SiMe3)2][.mu.-P(SiMe3)2])2, where M = zinc and cadmium, and their use in metalloorganic routes to Cd3P2 and MGeP2

✍ Scribed by Goel, Subhash C.; Chiang, Michael Y.; Buhro, William E.


Book ID
126210440
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
314 KB
Volume
112
Category
Article
ISSN
0002-7863

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## Abstract Reaction of [(Ξ·^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the Ξ·^3^‐1,2‐diphosphaallyl complexes [(Ξ·^5^‐C~5~H~5~)(CO)~2~M{Ξ·^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C

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