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Synthesis of homochiral 2-C-trifluoromethyl D-and L-ribose via trifluoromethylation of pentopyranosid-2-uloses

✍ Scribed by Uwe Eilitz; Christoph Böttcher; Lothar Hennig; Klaus Burger; Alois Haas; Simone Gockel; Joachim Sieler

Publisher
Journal of Heterocyclic Chemistry
Year
2003
Tongue
English
Weight
71 KB
Volume
40
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

Efficient syntheses of 2‐C‐trifluoromethyl D‐ and L‐ribose and some O‐glycosides via trifluoromethylation of D‐ and L‐3,4‐O‐isopropylidene‐β‐erythro‐pentopyranosid‐2‐ulose with Ruppert's reagent are described.

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