ChemInform Abstract: Synthesis of Hinder
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J.-P. BEGUE; D. BONNET-DELPON; D. BOUVET; M. H. ROCK
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Article
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2010
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John Wiley and Sons
⚖ 30 KB
Synthesis of Hindered and Functionalized 1-CF3 Substituted Olefins via a Carbolithiation-Elimination-Metalation Cascade. -Trisubstituted fluoroalkenes of type (III) are obtained stereoselectively. They react further with organolithium reagents and undergo vinyl metalation to give, after trapping wi