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Synthesis of highly symmetric mesomeric triazaphenalene betaines

✍ Scribed by Stanislav Kafka; Barbara Larissegger-Schnell; Thomas Kappe


Publisher
Journal of Heterocyclic Chemistry
Year
2004
Tongue
English
Weight
150 KB
Volume
41
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

The synthesis of seven mesomeric triazaphenalene betaines 4a‐g by condensation reaction of hexahydro‐2__H__‐pyrimido[1,2‐a]pyrimidine 1 with diethyl malonates 2a‐g or with bis(2,4,6‐trichlorophenyl)malonates 3c,f has been achieved. The guanidine 1 forms in benzene solution a salt with trimethyl methanetricarboxylate 5 which upon heating produces 4a.


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