ChemInform Abstract: Synthesis of New Conjugated Mesomeric Betaines from Alkoxycarbonylazinium Salts.
β Scribed by J. VALENCIANO; A. M. CUADRO; J. J. VAQUERO; J. L. GARCIA-NAVIO; J. ALVAREZ-BUILLA; P. GOMEZ-SAL; A. MARTIN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Synthesis of New Conjugated Mesomeric Betaines from Alkoxycarbonylazinium Salts.
-Treatment of the iodide (I), which is generated from 2-ethoxycarbonylpyridinium N-aminide, with aminoheterocycles leads to various mesomeric betaines like (III) and (VI). In some cases, however, desired betaines are not formed but associates like (VIII) arising from strong hydrogen bonding interactions. -(VALENCIANO,
π SIMILAR VOLUMES
Synthesis of Mesomeric Betaines, Quinoliziniumides, via Back-Donated 1,6-Cyclization. -3-Aminopyridinium salts (I) react with polarized olefins to form the corresponding 3-aminopyridinium N-allylides (III). Thermolysis in xylene or acetic acid affords the back-donated 1,6-cyclization products (IV)
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