✍ Scribed by Renji Okazaki; Kei Goto
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Application of novel bowl‐type and dendrimer‐type steric protection groups to the first synthesis of stable aromatic S‐nitrosothiols is described. These compounds showed remarkable thermal stability whereas they easily reacted with appropriate reagents. X‐ray crystallographic analysis established their structures, where the CSNO linkage adopts only the syn conformation. Synthesis of a stable sulfenic acid by taking advantage of the bowl‐type substituent is also delineated. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:414–418, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10068
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While the manifold aspects related to the chemistry of organic ozonides have been extensively studied,' the characterization of thio&.onides has not been reported.' We wish to
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