Synthesis of highly oxygenated carbocyclic derivatives: decalins and cyclohexanes from sugar allyltins
✍ Scribed by Sławomir Jarosz; Marcin Nowogródzki; Marta Kołaczek
- Book ID
- 108284275
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 203 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0957-4166
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
From Sugar Allyltins to Chiral Cyclopentadienes: Radical Cyclization of Highly Oxygenated Sugar-Derived Dienoaldehydes. -The title transformation leading to interesting cyclopentane derivatives is investigated. It is noteworthy that the cyclization of compounds (I), (III), (V), and (VII), gives onl
Secondary sugar allyltin derivatives of the D-series: Sug-CH(SnBu 3 )-CH CH 2 (obtained in an S N 2% reaction of the corresponding primary allylic mesylates with 'Bu 3 SnCu') with the S-configuration at the stereogenic center bearing the -SnBu 3 group decompose at 140°C to dienoaldehydes: CH 2 CH-CH