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ChemInform Abstract: From Sugar Allyltins to Chiral Cyclopentadienes: Radical Cyclization of Highly Oxygenated Sugar-Derived Dienoaldehydes.

✍ Scribed by M. MACH; S. JAROSZ

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

From Sugar Allyltins to Chiral Cyclopentadienes: Radical Cyclization of Highly Oxygenated Sugar-Derived Dienoaldehydes.

-The title transformation leading to interesting cyclopentane derivatives is investigated. It is noteworthy that the cyclization of compounds (I), (III), (V), and (VII), gives only one stereoisomer, whereas (IX) gives a mixture in which the cis-isomer is formed predominantly.

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