𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of higher sugars via allyltin derivatives of simple monosaccharides

✍ Scribed by Jarosz, Slawomir; Fraser-Reid, Bert


Book ID
121414746
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
298 KB
Volume
54
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Synthesis and thermal stability of secon
✍ Sławomir Jarosz; Katarzyna Szewczyk; Anna Zawisza 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 666 KB

Reaction of sugar allylic mesylates with tri-n-butyltin cuprate affords the primary and secondary allyltin derivatives: Sug-CH CH-CH 2 SnBu 3 and Sug-CH(SnBu 3 )-CH CH 2 with the latter predominating. The S N 2% addition led almost exclusively to one isomer with the S configuration at the newly crea