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Synthesis of heterocyclic propellanes via 1,3-dipolar cycloaddition reactions to bicyclo[5.3.0]dec-1(7)-en-2-onea

โœ Scribed by E. Coutouli-Argyropoulou; E. Malamidou-Xenikaki


Book ID
112128409
Publisher
Journal of Heterocyclic Chemistry
Year
1986
Tongue
English
Weight
253 KB
Volume
23
Category
Article
ISSN
0022-152X

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๐Ÿ“œ SIMILAR VOLUMES


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## Abstract __N__โ€Methylcycloalkano[__b__]indoles 1a, 1cโ€“d and __N__โ€methylindeno[1,2โ€__b__]indole (1e) react with 2,6โ€dichlorobenzonitrile oxide (2) to afford regioselectively propellanes 3. Catalytic hydrogenation of compounds 3 proceeds via the labile ฮฒโ€hydroxyimines 4, which are further decompo