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Synthesis of 8,9-oxaza[5.3.3]Propell-9-en-2-ones via 1,3-dipolar cycloaddition of nitrile oxides to bicyclo[5.3.0]Dec-1(7)-en-2-one

✍ Scribed by E. Malamidou-Xenikaki; E. Coutouli-Argyropoulou; N.E. Alexandrou


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
155 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis


Y= : The synthesis of the title heterocyclic propellanes is described. The cycloaddition is a so examined on the Gasis of frontier molecular orbitals (FMO) of the reacting species.

Although the synthesis of several propellanes' was achieved by Diels-Alder type reactions


πŸ“œ SIMILAR VOLUMES


The photochemistry of anti-tricyclo[5.2.
✍ Kazuyuki Yano πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 French βš– 101 KB

Recently, Cargill and coworkers1 have reported that irradiation of antitricyclo[5.2.0.0 285]nona-3,8-dien-9-one(I)l'2 in methylenechloride with "black-CI, lights" gives homocubane as a major product. However, it may be expected that