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Synthesis of Geodesic Polynuclear Arenes and Fullerenes by Intramolecular Aryl–Aryl Coupling

✍ Scribed by Prof. Carlo Thilgen

Book ID
112001390
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
288 KB
Volume
51
Category
Article
ISSN
0044-8249

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Aryl triflates react with higher order nixed cuprates R2Cu(CN)Li2 to produce arenes in good yield. The aryl ring nay have either an electron-donating or an electron-withdrawing substituknt; the organocuprate may be either primary, aryl, or vinyl. We reported 1,2 recently a new method of regiospecif