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Metal-free synthesis of aryl esters by coupling aryl carboxylic acids and aryl boronic acids

✍ Scribed by Ruso, Jayaraman Sembian; Rajendiran, Nagappan; Kumaran, Rajendran Senthil


Book ID
122945563
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
618 KB
Volume
55
Category
Article
ISSN
0040-4039

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Palladium(II) acetate and N, N-bis-(2,6-diisopropylphenyl)dihydroimidazolium chloride (2 mol%) were used to catalyze the carbonylative coupling of aryl diazonium tetrafluoroborate salts and aryl boronic acids to form aryl ketones. Optimal conditions include carbon monoxide (1 atm) in 1,4-dioxane at