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Synthesis of Fused Oxabicyclic Systems by Metal-Catalyzed Intramolecular Addition of 1,3-Cycloalkyldiones to Alkynes

✍ Scribed by Gulías, Moisés; Rodríguez, J. Ramón; Castedo, Luis; Mascareñas, José L.


Book ID
121200426
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
52 KB
Volume
5
Category
Article
ISSN
1523-7060

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Intramolecular carbenoid addition to 1,3
✍ T. Hudlicky; J.P. Sheth; V. Gee; D. Barnvos 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 342 KB

Diazoketones containing a 1,3-diene moiety were decomposed to yield corresponding vinylcyclopropanes stereospecifically. Transformation of vinylcyclopropanes to cyclopentenes is described and the scope of the reaction is discussed. The intramolecular addition of carbenoids to conjugated dienes has n