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Synthesis of Fused Bicyclic Imidazoles by Sequential Van Leusen/Ring-Closing Metathesis Reactions

✍ Scribed by Gracias, Vijaya; Gasiecki, Alan F.; Djuric, Stevan W.


Book ID
125462704
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
83 KB
Volume
7
Category
Article
ISSN
1523-7060

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Synthesis of fused bicyclic imidazoles b
✍ Yingzhong Chen; H.V.Rasika Dias; Carl J. Lovely πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 364 KB

The preparation of a number of dienylimidazole via chemoselective metal-halogen exchange and their utility in ring-closing metathesis is described. Essentially all regioisomeric permutations participate in metathesis with the notable exception of 4-vinyl-5-allylimidazoles, provided that the imidazol