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Synthesis of Fused 1-Sila-, 1-Germa-, and 1-Selenacyclohepta-2,4,6-trienes

✍ Scribed by Shirani, Hamid; Janosik, Tomasz

Book ID
127339502
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
89 KB
Volume
27
Category
Article
ISSN
0276-7333

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✍ Klaus Banert; Frank KΓΆhler; Klaus Kowski; Barbara Meier; Beate MΓΌller; Paul Rade πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 120 KB

1-Azaspiro[2.4]hepta-1,4,6-trienes 3a-c have been prepared by photolysis or thermolysis of 6-azidofulvenes 5a-c, which were accessible by nucleophilic substitution reactions of the precursors 4a,b or by nucleophilic addition of hydrazoic acid to ethenylidene-cyclopentadiene (6c). The UV photoelectro