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Synthesis of Functionalized Polytriazoles via One-Pot Sequential Copper-Catalyzed Azide–Alkyne [3+2] Cycloaddition and Atom Transfer Radical Addition (ATRA)

✍ Scribed by Carolynne L. Ricardo; Tomislav Pintauer

Book ID
112101967
Publisher
Laser Pages Publishing Ltd.
Year
2012
Tongue
English
Weight
658 KB
Volume
52
Category
Article
ISSN
0021-2148

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One-Pot Sequential Azide–Alkyne [3+2] Cy
One-Pot Sequential Azide–Alkyne [3+2] Cycloaddition and Atom Transfer Radical Addition (ATRA): Expanding the Scope of In Situ Copper(I) Regeneration in the Presence of Environmentally Benign Reducing Agent
✍ Carolynne L. Ricardo; Tomislav Pintauer 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 437 KB 👁 1 views

## Abstract One‐pot sequential reactions involving azide–alkyne [3+2] cycloaddition and atom transfer radical addition (ATRA) catalyzed by [Cu^II^(TPMA)X][X] {X = Br^–^ or Cl^–^, TPMA = tris(2‐pyridylmethyl)amine} in the presence of ascorbic acid as a reducing agent are reported. Reactions with azi