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One-pot synthesis of photosensitive dendrimer-like polystyrenes from simultaneous copper(I)-catalyzed azide–alkyne cycloaddition and atom transfer radical polymerization

✍ Scribed by Fang Yao; Li-Qun Xu; Guo-Dong Fu; Bao-Ping Lin

Book ID: 112174531
Publisher: John Wiley and Sons
Year: 2012
Tongue: English
Weight: 951 KB
Volume: 61
Category: Article
ISSN: 0959-8103
DOI: 10.1002/pi.4134

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## Abstract One‐pot sequential reactions involving azide–alkyne [3+2] cycloaddition and atom transfer radical addition (ATRA) catalyzed by [Cu^II^(TPMA)X][X] {X = Br^–^ or Cl^–^, TPMA = tris(2‐pyridylmethyl)amine} in the presence of ascorbic acid as a reducing agent are reported. Reactions with azi