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Synthesis of Functionalized Allenamides from Ynamides by Enolate Claisen Rearrangement

โœ Scribed by Brioche, Julien; Meyer, Christophe; Cossy, Janine

Book ID
120173749
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
339 KB
Volume
15
Category
Article
ISSN
1523-7060

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Allyloxy ketone enol ether-claisen rearr
Allyloxy ketone enol ether-claisen rearrangement. regiospecific synthesis of allyl ketones from allyl alcohols
โœ Joseph L.C. Kachinski; Robert G. Salomon ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Claisen rearrangement of ally1 vinyl ethers is an important general method of carboncarbon bond formation for synthesis of y,b-unsaturated aldehydes and ketones. 1 Syntheses of y,b-unsaturated esters and amides are similarly achieved by rearrangements of 2-alkoxy and 2amino-3-oxa-1,5-hexadienes.