Synthesis of Functionalized 1,5-Cyclooctadienes by LICKOR Metalation.
✍ Scribed by Jefferson D. Revell; A. Ganesan
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 83 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The kinetics and mechanism of the liquid phase ketonization of 1,5‐cyclooctadiene (COD) by nitrous oxide have been studied. The reaction proceeds without catalyst in the temperature range 473–553 K with the activation energy 113 kJ mol^−1^ and is first order with respect to the initial
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## Abstract In contrast to the addition of iodine azide to cyclooctene (1) or 1,3‐cyclooctadiene (5), its reaction with 1,5‐cyclooctadiene (12) leads mainly to the surprisingly stable tetraazido‐substituted 2‐tetrazene 14 The structure of this was established by ^15^N‐NMR studies and an X‐ray struc