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Synthesis of a Tetraazido-Substituted 2-Tetrazene from 1,5-Cyclooctadiene and Iodine Azide

✍ Scribed by Rose, Bernd ;Schollmeyer, Dieter ;Meier, Herbert

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
400 KB
Volume
1997
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

In contrast to the addition of iodine azide to cyclooctene (1) or 1,3‐cyclooctadiene (5), its reaction with 1,5‐cyclooctadiene (12) leads mainly to the surprisingly stable tetraazido‐substituted 2‐tetrazene 14 The structure of this was established by ^15^N‐NMR studies and an X‐ray structural analysis. Treatment of 14 with hydrochloric acid yields the diazido‐substituted 9‐azabicyclo[3.3.1]nonane 20.

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