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Synthesis of Ferrocenyl Deoxyribonucleic Acids (DNAs) and Their Application to Electrochemical Gene Detection

✍ Scribed by Kosuke Mukumoto; Shigeori Takenaka

Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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An efficient and flexible asymmetric synthesis of planar chiral ferrocenyl ligands bearing a stereogenic centre at the Ξ²-position to the metallocene backbone is described. A variety of donor groups can be independently introduced as electrophiles, thus allowing electronic and steric fine-tuning of t