𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of farnesylacetic acid-14C and its geraniol ester (Gefarnate-14C)

✍ Scribed by Masaaki Hazue; Kunio Miyake; Michio Endo

Publisher
John Wiley and Sons
Year
1969
Tongue
French
Weight
483 KB
Volume
5
Category
Article
ISSN
0022-2135

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of geraniol-7−14C
Synthesis of geraniol-7−14C
✍ H. D. Durst; E. Leete 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 French ⚖ 201 KB

Gerani01-7-~~C has been synthesized in an overall yield of 46 x, starting with acetone-2-14C. INTRODUCTION.

Synthesis of daunorubicin-14-14C and adr
Synthesis of daunorubicin-14-14C and adriamycin-14-14C
✍ C. Rolland Chen; Mary Tan Fon; Alan N. Fujiwara; David W. Henry; Morris A. Leaff 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 French ⚖ 275 KB

## Abstract Reaction of adriamycinone with excess ^14^CH~3~Mgl and periodate cleavage of the resulting glycol (5) affords daunomycinone‐14‐^14^C (6). Bromination and hydrolysis of 6 gives adriamycinone‐14‐^14^C (8). Coupling of 6 and the 14‐0‐p‐anisyldiphenyl‐methyl derivative (9) with 1‐chloro‐3‐N

Synthesis of 2,4-dihydroxy-6-pentyl-benz
Synthesis of 2,4-dihydroxy-6-pentyl-benzoic-6-14C acid, ethyl ester. (olivetolic-6-14C acid. ethyl ester)
✍ J. P. Schmit; V. Van de Velde; M. Piraux 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 French ⚖ 222 KB

## Abstract In a first step, Δ1‐trans‐octenoic‐3‐^14^C acid was prepared by a Grignard reaction with BaCO~3~‐^14^C and 1‐bromo‐pentane, followed by reduction of the obtained hexanoic‐1‐^14^C acid to hexanal‐1‐^14^C via the n‐hexanol‐1‐^14^C. The produced hexanal‐1‐^14^C, by condensing with malonic