Synthesis of exo- and endobrevicomines from 1,1,5-trichloro-1-pentene
β Scribed by L. I. Zakharkin; I. M. Churilova
- Book ID
- 112442728
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 190 KB
- Volume
- 33
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
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## Abstract 1βPenteneβ4β^14^C and 1βpenteneβ5β^14^C were obtained in one single step from iodoethaneβ1β^14^C and iodoethaneβ2β^14^C, respectively, by reaction with allylmagnesium chloride in tetrahydrofurfuroxytetrahydropyran (TFTP) as solvent. The synthesis was carried out on a twenty mmoles scale
By mistake wrong concentrations were given in the footnote of Table 1 and in the Discussion. Instead of c 0 Ο 1.2 ο read c 0 Ο 0.12 ο if 2-naphthalenethiol was used as hydrogen donor and instead of c 0 Ο 1.8 ο read c 0 Ο 0.18 ο if Bu 3 SnH was used to trap photoproducts. In Table 2 relative rate con