Synthesis of epothilones B and D from d-glucose
β Scribed by Mikhail S Ermolenko; Pierre Potier
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 176 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Reaction of a 4: 1 mixture of D-ribono-and D-arabinono-I ,4-lactones with benzaldehyde and hydrochloric acid gave 59% crystalline 3,4-O-benzyhdene-D-ribono-1,5-lactone. This acetal was oxidized with manganese dioxide in acetone to its 2-keto derivative (6) in 76% yield. Acid-catalyzed methanolysis