𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of End-Functionalized Polymer by Means of Anionic Living Polymerization. 6. Synthesis of Well-Defined Polystyrenes and Polyisoprenes with 4-Vinylphenyl End Group

✍ Scribed by Hirao, Akira; Hayashi, Mayumi; Nakahama, Seiichi


Book ID
127378588
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
197 KB
Volume
29
Category
Article
ISSN
0024-9297

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Synthesis of end-functionalized polymer
✍ Kenji Sugiyama; Akira Hirao; Seiichi Nakahama 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 916 KB

## Abstract Reactions of anionic living polymers of styrene, __tert__‐butyl methacrylate, and 2‐(trimethylsiloxy)ethyl methacrylate with perfluoroalkyl (Rf) halides, such as C~4~F~9~(CH~2~)~3~I(1), (CF~3~)~2~CF(CF~2~)~6~I (2), C~4~F~9~(CH~2~)~2~I (3), C~8~F~17~(CH~2~)~2~O(CH~2~)~4~Br (4), were inve

Synthesis of end-functionalized polymers
✍ Katsuhiko Takenaka; Akira Hirao; Seiichi Nakahama 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB

Both polystyrenes and polyisoprenes with 1,3-butadienyl end-groups were synthesized by the reactions of polystyryl and polyisoprenyl anions with 6-bromo-3-methylene-1 -hexene (3). The 1,3-butadienyl end-group was further transformed to an anhydride function by Diels-Alder reaction with maleic anhydr

Synthesis of end-functionalized polymer
✍ Mieko Tohyama; Akira Hirao; Seiichi Nakahama; Katsuhiko Takenaka 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 773 KB

## Abstract Anionic living polystyrene and polyisoprene were allowed to react with six __tert__‐butyl‐dimethylsilyl ethers of ω‐halo‐1‐alkanols 1–6, the trimethylsilyl ether of bromohydrin (7), the __tert__‐butyldimethylsilyl ether of 4‐bromophenol (8), and __tert__‐butyldimethylsilyl 3‐chloropropy