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Synthesis of Enantiopure 1-r-Aryl-2-c,5-t-diphenylphospholane Oxides and Boranes by Pd-Catalyzed C–P Bond Formation

✍ Scribed by Martial Toffano; Cristian Dobrota; Jean-Claude Fiaud

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 152 KB
Volume: 2006
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200500577

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✦ Synopsis

Abstract

New chiral enantiopure phospholane oxides 1 and boranes 5 were obtained from efficient carbon–phosphorus bond formation by organocuprate or palladium‐catalyzed reactions. C–P cross‐coupling reactions between chiral phosphane oxide 3 or borane 4 and various aryl derivatives are presented.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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