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Synthesis of Enantiopure 1-r-Aryl-2-c,5-t-diphenylphospholane Oxides and Boranes by Pd-Catalyzed C—P Bond Formation.

✍ Scribed by Martial Toffano; Cristian Dobrota; Jean-Claude Fiaud

Publisher
John Wiley and Sons
Year
2006
Weight
35 KB
Volume
37
Category
Article
ISSN
0931-7597

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Abstract

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Synthesis of Enantiopure 1-r-Aryl-2-c,5-
Synthesis of Enantiopure 1-r-Aryl-2-c,5-t-diphenylphospholane Oxides and Boranes by Pd-Catalyzed C–P Bond Formation
✍ Martial Toffano; Cristian Dobrota; Jean-Claude Fiaud 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 152 KB

## Abstract New chiral enantiopure phospholane oxides **1** and boranes **5** were obtained from efficient carbon–phosphorus bond formation by organocuprate or palladium‐catalyzed reactions. C–P cross‐coupling reactions between chiral phosphane oxide **3** or borane **4** and various aryl derivativ