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Synthesis of enantiomerically pure fire ant venom alkaloids: Solenopsins and isosolenopsins A, B and C

✍ Scribed by H. M. T. Bandara Herath; N. P. Dhammika Nanayakkara

Publisher: Journal of Heterocyclic Chemistry
Year: 2008
Tongue: English
Weight: 506 KB
Volume: 45
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.5570450112

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✦ Synopsis

Abstract

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Concise and efficient methods for the synthesis of enantiomers of fire ant venom alkaloids solenopsin and isosolenopsin A, B, and C are described. These syntheses are based on diastereoselective electrophilic substitution of enatiomerically‐pure α‐lithiated 2‐alkylpiperidine.

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