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Synthesis of enantiomerically pure 7-oxabicyclo[2.2.1]hept-2-enes precursors in the preparation of taxol analogues

✍ Scribed by Viviane Theurillat-Moritz; Pierre Vogel


Book ID
103977685
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
391 KB
Volume
7
Category
Article
ISSN
0957-4166

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The Preparation of Optically Pure 7-Oxab
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Dedicated to Prof. Ch. Tamm on the occasion of his 60th birthday (12.4.83) ## Summary (-)-1-Camphanoyloxyacrylonitrile (= (-)-1 -cyanovinyl camphanate; 1) obtained from the commercially available ( -)-camphanoyl chloride and 2-0x0propiononitrile added to furan at 20" in the presence of CU(BF,)~.