Synthesis of DL-tyroslne-2′-t and tyramine-2′-t
✍ Scribed by P. W. Jeffs; N. Johns; D. B. Johnson
- Book ID
- 102368975
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- French
- Weight
- 433 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0022-2135
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Lithiation of 4‐benzyloxy‐2‐bromotoluene and subsequent quenching of the lithiated product affords 4‐benzyloxytoluene‐2‐t which is oxidized directly to 4‐benzyloxybenzaldehyde‐2‐t with ceric ammonium nitrate. Transformation of the aldehyde 6 by standard procedures affords DL‐tyrosine‐2′‐t and tyramine‐2′‐t.
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