The first total synthesii of the highly unstable biological medistor 12-ket&coss&etr~ic acid (12-KBTB) 3 and its 89-traas -isoma tp is presented. The strategy focuses on the stable precursor dithiane u and its ccnwzsion to gand 211. Bicchemical experiments show that the two isomers are net interccmv
β¦ LIBER β¦
Synthesis of dl-mesembrine and its trans isomer
β Scribed by Tokuro Oh-ishi; Hiroshi Kugita
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 191 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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