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Synthesis of dipotassium dimethylsilanediolate monohydrate

✍ Scribed by Stephen Clarke; Janis G. Matisons; Michael J. Owen; Dan Graiver

Book ID
110398155
Publisher
Springer
Year
2002
Tongue
English
Weight
112 KB
Volume
1
Category
Article
ISSN
1569-0660

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Dipotassium ethane-1,1-diylbisΒ­(diazeniu
Dipotassium ethane-1,1-diylbisΒ­(diazeniumdiolate) monohydrate
✍ Arulsamy, Navamoney ;Bohle, D. Scott πŸ“‚ Article πŸ“… 2005 πŸ› International Union of Crystallography 🌐 English βš– 186 KB

The ethane-1,1-bis(diazeniumdiolate) anion in the title compound, 2K + ÁC 2 H 4 N 4 O 4 2Γ€ ÁH 2 O, acts as a complex bridging ligand. Both the N and the O atoms of the diazeniumdiolate substituents are coordinated to the K + cations, revealing the delocalization of a negative charge over the four-at