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Synthesis of di(2-bromoalkyi) disulfides by electrophilic addition of dithiobisamines to olefins

✍ Scribed by N. V. Zyk; E. K. Beloglazkina; N. S. Zefirov

Book ID
112537848
Publisher
Springer
Year
1996
Tongue
English
Weight
415 KB
Volume
45
Category
Article
ISSN
1573-9171

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Acetylenes react with bis(pyridine)iodo(I) tetrafluoroborate (1) in the presence of a wide variety of nucleophiles (F,Cl,Br,I,SCN,pyridine,OAc,anisole,H) to give 1,2iodofunctionalized olefins (4).