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A new electrophilic addition to acetylenes. Synthesis of 1,2-iodofunctionalized olefins

✍ Scribed by José Barluenga; Miguel A Rodríguez; José M González; Pedro J Campos; Gregorio Asensio

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 222 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84782-6

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✦ Synopsis

Acetylenes react with bis(pyridine)iodo(I) tetrafluoroborate (1) in the presence of a wide variety of nucleophiles (F,Cl,Br,I,SCN,pyridine,OAc,anisole,H) to give 1,2iodofunctionalized olefins (4).

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