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Synthesis of (−)-Deoxoprosophylline, (+)-2- epi -Deoxoprosopinine, and (2 R ,3 R )- and (2 R ,3 S )-3-Hydroxypipecolic Acids from d -Glycals

✍ Scribed by Kokatla, Hari Prasad; Lahiri, Rima; Kancharla, Pavan K.; Doddi, Venkata Ramana; Vankar, Yashwant D.


Book ID
121256844
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
858 KB
Volume
75
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES


An alternative stereoselective synthesis
✍ Mansour Haddad; Marc Larchevêque 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 71 KB

The enantioselective synthesis of trans-(2R,3R)-3-hydroxypipecolic acid 1b is presented, starting from O-protected methyl mandelate as chiral source. The synthesis involved a regioselective intramolecular nucleophilic substitution of an azido epoxide as the key step .