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Synthesis of D-3,4-di-O-methyl-erythritol 1

✍ Scribed by Goldstein, Irwin J.; Smith, F.


Book ID
126129773
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
420 KB
Volume
79
Category
Article
ISSN
0002-7863

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Synthesis of allyl and benzyl 4-O-(3,6-d
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Condensation of 2,4-di-O-acetyl-3,6-di-O-methyl-a-~glucopyranosyl bromide with either ally1 or benxyl2,4-di-0-methyl-cu+rhamnopyranoside in the presence of mercuric cyanide, followed by 0-deacetylation, gave the title oligosaccharides in excellent yields.