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Synthesis of cyclopropylphosphonates on the basis of catalytic [1+2] cycloaddition of diazomethylphosphonic esters to alkenes

✍ Scribed by Yashin, N. V.; Chemagin, A. V.; Grishin, Yu. K.; Kuznetsova, T. S.; Zefirov, N. S.


Book ID
120641363
Publisher
Springer
Year
2013
Tongue
English
Weight
198 KB
Volume
450
Category
Article
ISSN
0012-5008

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l-Seleno-2-silylethene 1 undergoes stereoseleetive SnCl,-promoted [2+1] cycloaddition reactions with 2-phosphonoacrylates 2 in high yields; the resulting highly functionalized cyclopropanephosphonic acid ester products 3 are versatile starting materiak for biologically important compounds. 0 1997Els