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Synthesis of cyclohexakis- and cycloheptakis-(1 → 4)-(7-amino-6,7-dideoxy-α-d-gluco-heptopyranosyl), homoanalogues of 6-amino-6-deoxy-cyclomaltooligosaccharides

✍ Scribed by Jacques Defaye; Andrée Gadelle


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
312 KB
Volume
265
Category
Article
ISSN
0008-6215

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Synthesis of a cycloheptaose consisting
✍ Hans H. Baer; Yaping Shen; Francisco Santoyo González; Antonio Vargas Berenguel; 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 888 KB

Approaches to chain extension at the C-6 positions in cyclomaltoheptaose (1) were examined with the aim of producing novel /3-cyclodextrin analogs composed of heptose or hepturonic acid units. Iron carbonyl-mediated methoxycarbonylation, and nucleophilic displacement by cyanide, in the fully acetyla