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Chemical synthesis of 4-deoxy-(1→6)-α-d-xylo-hexopyranan and 3,4-dideoxy-(1→6)-α-d-erythro-hexopyranan

✍ Scribed by Masahiko Okada; Ayako Banno; Hiroshi Sumitomo


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
585 KB
Volume
226
Category
Article
ISSN
0008-6215

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4,6-Di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranose (4,6-di-o-acetyl-D-pseudoglucal), prepared from 3,4,6-tri-O-acetyl-1,5-anhydro-2-deoxy-D-arubinohex-1-enitol (tri-0-acetyl-D-glucal), was condensed, by catalysis with boron trifluoride, with an equivalent of the original glycal, to give crystal